An improved process for preparing regioregular substituted polythiophenes is described where a substituted thiophene having at least two leaving groups is treated with an organomagnesium halide followed by zinc chloride or bromide and the resulting reaction mixture in solution is polymerized with a Ni(II) catalyst.
An improved process for preparing regioregular substituted polythiophenes is described where a substituted thiophene having at least two leaving groups is treated with an organomagnesium halide followed by zinc chloride or bromide and the resulting reaction mixture in solution is polymerized with a Ni(II) catalyst.
The invention includes compounds of formula I:wherein X is —ZnBr, —ZnCl, or —ZnI; A is an aryl, or heteroaryl; Y is C-Calkyl; and Z is a N containing heteroaryl that is bonded by the N. The invention also includes combinatorial libraries made using at least one compound of the invention.
Process For Preparation Of Regioregular Poly(3-Substituted-Thiophene)
The invention provides a method of preparing regioregular HT poly(3-substituted-thiophene). The method includes contacting a 3-substituted-thiophene-metal complex with a manganese(II) halide to provide a 3-substituted-thiophene-manganese complex; and contacting the thiophene-manganese complex with a nickel(II) catalyst to provide the regioregular HT poly(3-substituted-thiophene). The substitution at the 3-position can be a variety of different groups. Additionally, unsubstituted and 3,4-disubstituted polythiophenes can also be prepared by the method. Electronic devices can be made using the polymers prepared as described herein.
Embodiments of the invention relate to a galvanic cell comprising a first electrode, a second electrode, an electrolyte in contact with both the electrodes, a substrate adapted to support and separate the electrodes while allowing the electrolyte to move within it and contacts electrically coupled to the electrodes, wherein one or more of the electrodes comprises one or more highly reactive metals and wherein at least one of the electrodes is printed on the substrate.
BASF SE - LUDWIGSHAFEN RIEKE METALS, INC. - LINCOLN NE
International Classification:
H01B 5/00 C08G 75/00
US Classification:
1741261, 528378
Abstract:
Methods of preparing conducting polymers and the conductive polymers prepared therefrom are provided. Electronic devices can be made using the polymers prepared as described herein. A method of preparing a conducting polymer is disclosed comprising: combining a di(C-C)alkyl metal reagent together with a first dihalo-monomer and an optional second dihalo-monomer to form a monomer-metal complex; and combining the monomer-metal complex together with a metal catalyst to provide the conducting polymer, wherein each dihalo-monomer is independently an aromatic or heteroaromatic group substituted by two halogens wherein the halogens are the same or different.
BASE SE - Ludwigshafen RIEKE METALS, INC. - Lincoln NE
International Classification:
B01J 41/12
US Classification:
521 25
Abstract:
Methods of preparing conducting polymers and the conductive polymers prepared therefrom are provided. The method includes a) combining a monomer-metal complex together with a manganese (II) halide to provide a monomer-manganese complex, and b) combining the monomer-manganese complex together with a metal catalyst to provide the conductive polymer. Electronic devices can be made using the polymers prepared as described herein.
Name / Title
Company / Classification
Phones & Addresses
Reuben D. Rieke President, Director
Rieke Metals, LLC Chemicals · Whol Chemicals/Products Commercial Physical Research